cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN 3)phenyl]tetrazolido}manganese(II) dihydrate
نویسندگان
چکیده
In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the Mn(2+) lies on a twofold rotation axis and is six-coordinated by two N atoms from the cis-related monodentate 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four O atoms from the coordinated water mol-ecules. The complex mol-ecules are connected via water O-H⋯O and O-H⋯N hydrogen bonds and weak π-π stacking inter-actions between the benzene rings [minimum ring centroid separation = 3.750 (6) Å] into a three-dimensional polymeric structure. The imidazolyl group of the ligand is partially disordered over two sets of sites with refined occupancies of 0.531 (7):0.469 (7).
منابع مشابه
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN 3)phenyl]tetrazolido}manganese(II) dihydrate
In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the complex unit comprises an Mn(2+) ion, coordinated by two imidazole N atoms from cis-related monodentate 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four water mol-ecules, together with two water mol-ecules of solvation. The Mn(2+) ion lies on a twofold rotation axis and has a slightly distorted octa-hedral geometry. Th...
متن کاملTetraaquabis{5-[4-(imidazol-1-yl-κN 3)phenyl]tetrazolido}manganese(II)
In the title complex, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)], the Mn(2+) cation is located on a twofold rotation axis and is coordinated by two N atoms from two 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four O atoms from four water mol-ecules, displaying a distorted MnN(2)O(4) octa-hedral geometry. The crystal structure is stabilized by intermolecular O-H⋯N hydrogen bonds involving the coo...
متن کاملTetraaquabis[5-(pyridin-3-yl)tetrazolido-κN 5]manganese(II) tetrahydrate
The title compound, [Mn(C₆H₄N₅)₂(H₂O)₄]·4H₂O, was obtained by the solution reaction of MnCl₂ and 3-(2H-tetra-zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa-hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra-zolide ligands occupying trans positions and four water mol-ecules. In the crystal, the mononuclea...
متن کاملDiaquabis[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN 3)nicotinato-κN]manganese(II)
In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol-ecules in a distorted octa-hedral environment. Inter-molecular O-H⋯O hydrogen bonds lead to a chain along [010]. Intra-molecular N-H⋯O and O-H⋯O hydrogen bonds are observed.
متن کاملTetrakis{1-[4-(1H-imidazol-1-yl-κN 3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II)
The title complex mol-ecule, [Ni(NCS)(2)(C(11)H(10)N(2)O)(4)], has a crystallographically imposed centre of symmetry. The Ni(II) atom is coordinated by the N atoms of two trans-arranged NCS(-) anions and four 1-[4-(1H-imidazol-1-yl)phen-yl]ethan-one ligands in a distorted octa-hedral geometry. In the crystal, C-H⋯S hydrogen bonds link the complex mol-ecules into chains parallel to the b axis. T...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012